Tetrahedron Letters p. 1381 - 1382 (1989)
Update date:2022-08-05
Topics:
Barton, D.H.R
Boivin, J.
Gaudin D.
Jankowski, K.
Oxidation of various tertiary amines by the GifIV system based on iron catalyst associated with a reductant (zinc) and molecular oxigen, led to a mixture of the keto-derivatives and the corresponding lactams.Steric hindrance and electron withdrawing substituents exert a deactivating effect on the oxidation.
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