Mechanistic Studies of Diastereoselective Cyclopropanation via Homochiral Ketals. 1. Dioxolane Structural Effects

DOI: 10.1021/jo00294a016

Source and publish data:

Journal of Organic Chemistry p. 2045 - 2055 (1990)

Update date:2022-07-29

Topics: Mechanistic Studies

Authors:

Mash, Eugene A.

Hemperly, Susan B.

Nelson, Keith A.

Heidt, Philip C.

Deusen, Shawne Van

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Article abstract of DOI:10.1021/jo00294a016

Compounds structurally related to 2-cyclohexen-1-one 1,4-di-O-benzyl-L-threitol ketal were prepared and subjected to the Simmons-Smith cyclopropanation.From these experiments a mechanistic model for diastereoselective cyclopropanation of common ring syste

Full text of DOI:10.1021/jo00294a016

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Product name:2-cyclohexen-1-one 1,4-di-O-(4-biphenylylmethyl)-L-threitol ketal

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