Chiral Cooperativity: The Nature of the Diastereoselective and Enantioselective Step in the Gold(I)-Catalyzed Aldol Reaction Utilizing Chiral Ferrocenylamine Ligands

DOI: 10.1021/jo00292a046

Source and publish data:

Journal of Organic Chemistry p. 1649 - 1664 (1990)

Update date:2022-09-26

Topics:

Authors:

Togni, Antonio

Pastor, Stephen D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00292a046

Mechanistic aspects of the gold(I)-catalyzed aldol reaction of aldehydes with α-isocyanoacetate esters in the presence of a chiral ferrocenylamine ligand possessing both planar and central chirality were investigated.The synthesis of (S)-N-<2-(N,N-dimethy

Full text of DOI:10.1021/jo00292a046

Products guided by the article

Product name:trans-4-(Ethoxycarbonyl)-5-<2-(trifluoromethyl)phenyl>-2-oxazoline

Cas No:125251-33-4

R&D Labs maybe for 125251-33-4

Jingzhou TianHe Sci&Tech Chemical Co., Ltd.

Contact:86-716-8331612

Address:Jiangjin Road, #18, High-grade technology industries development district, Jingzhou city, Hubei province
Shanghai ZaiQi Bio-Tech Co., Ltd.,

Contact:+86-21-5482 4098

Address:Bldg. No.7, No.201 MinYi Rd，Songjiang CaoHeJing High-Tech Park Shanghai 201516 P,R,China
HANGZHOU PANYU CHEMICAL CO.,LIMITED

Contact:+86-571-86578491

Address:Rm 605, NO.1870 Binsheng Road,Binjiang Dist, Hangzhou, China
Suzhou ATL Chemical Co.,ltd

Contact:+86-0512-69209969

Address:Room 317,Lushan Road,Suzhou New District,Jiangsu Province,China.
Shenzhen Sungening Medicine Co., Ltd

Contact:+86-871-65110906

Address:Room702, Building 2, 365 Dianchi Road, Kunming, Yunnan Province, P.R. China

Relevant to this article

Iron(ii)-folded single-chain nanoparticles: a metalloenzyme mimicking sustainable catalyst for highly enantioselective sulfa-Michael addition in water

Doi:10.1039/d0gc00949k
(2020)
A Versatile One-Pot Access to Cyanoarenes from ortho- and para-Quinones: Paving the Way for Cyanated Functional Materials

Doi:10.1002/chem.201600004
(2016)
Pd(OAc)₂-catalyzed oxidative C-H/C-H cross-coupling of electron-deficient polyfluoroarenes with simple arenes

Doi:10.1021/ja109383e
(2010)
Thio analogs of pyrimidine bases: Synthesis and spectroscopic study of new potentially biologically active disulfides of N,O-(N,N- or O,O-)-Di- and N,N,O-Tri-(o-, m-, and p-)bromobenzyl-2-thiouracils

Doi:10.1080/10426500903501470
(2010)
A FACILE ROUTE TO HOMOCHIRAL SULFOXIDES

Doi:10.1016/S0040-4039(01)80467-6
(1989)
Targeted mass spectrometry-based approach for protein-ligand binding analyses in complex biological mixtures using a phenacyl bromide modification strategy

Doi:10.1021/acs.analchem.6b02658
(2016)

Article Doi