Chiral Cooperativity: The Nature of the Diastereoselective and Enantioselective Step in the Gold(I)-Catalyzed Aldol Reaction Utilizing Chiral Ferrocenylamine Ligands

DOI: 10.1021/jo00292a046

Source and publish data:

Journal of Organic Chemistry p. 1649 - 1664 (1990)

Update date:2022-09-26

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Authors:

Togni, Antonio

Pastor, Stephen D.

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Article abstract of DOI:10.1021/jo00292a046

Mechanistic aspects of the gold(I)-catalyzed aldol reaction of aldehydes with α-isocyanoacetate esters in the presence of a chiral ferrocenylamine ligand possessing both planar and central chirality were investigated.The synthesis of (S)-N-<2-(N,N-dimethy

Full text of DOI:10.1021/jo00292a046

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