Epoxidation Catalysed by Mn IIITPPCl using Dioxygen Activated by a System Containing N-Hydroxyphtalimide and Styrene, 2-Norbornene or Indene

DOI: 10.1039/P29890000951

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 951 - 956 (1989)

Update date:2022-07-29

Topics:

Authors:

Ozaki, Shigeko

Hamaguchi, Tomomi

Tsuchida, Keiichi

Kimata, Yukio

Masui, Masaichiro

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Article abstract of DOI:10.1039/P29890000951

The catalytic epoxidation of alkenes by molecular oxygen activated in the system containing N-hydroxyphtalimide (NHPI) and active alkenes such as styrene, 2-norbornene or indene is reported.The transient intermediates, alkyl hydroperoxides formed by autooxidation of NHPI and the active alkenes are proposed as oxygen sources which transfer mono-oxygen to Mn^IIITPPCl.

Full text of DOI:10.1039/P29890000951

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