Epoxidation Catalysed by Mn IIITPPCl using Dioxygen Activated by a System Containing N-Hydroxyphtalimide and Styrene, 2-Norbornene or Indene

DOI: 10.1039/P29890000951

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 951 - 956 (1989)

Update date:2022-07-29

Topics:

Authors:

Ozaki, Shigeko

Hamaguchi, Tomomi

Tsuchida, Keiichi

Kimata, Yukio

Masui, Masaichiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P29890000951

The catalytic epoxidation of alkenes by molecular oxygen activated in the system containing N-hydroxyphtalimide (NHPI) and active alkenes such as styrene, 2-norbornene or indene is reported.The transient intermediates, alkyl hydroperoxides formed by autooxidation of NHPI and the active alkenes are proposed as oxygen sources which transfer mono-oxygen to Mn^IIITPPCl.

Full text of DOI:10.1039/P29890000951

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:N-(3-hydroxyindan-2-yloxy)phtalimide

Cas No:125349-04-4

R&D Labs maybe for 125349-04-4

H&Y International Group Ltd

Contact:+86-571-86491666

Address:SHI XIANG ROAD
Jinan Decheng Hemu Medical Technology Co.，Ltd.

Contact:+86-531-68650525

Address:NO.554 Zhengfeng Road High-new Technology Development Zone
SHUNYUANSHENG BIO-PHARMTECH CO., LTD

website:https://www.whsysbio.com

Contact:--

Address:Building 13, Liandong U Valley-Wuhan Economic Innovation Valley, No. 259, Xingsan Road, Shamao Street, Hannan District, Wuhan City, Hubei Province
Jiangxi Huashi Pharmaceutical Co., Ltd

Contact:+86-795-4509628

Address:Ningbo Ave., Fengtian Industrial Park, Fengxin Country, Jiangxi, China.
PINGYUAN SIHUAN PHARMACEUTICAL CO., LTD

Contact:+86-531-55696072

Address:#2766,yinxiu Road, Economic Development Zone, Pingyuan Country, Shandong Province, China.

Relevant to this article

A synthetic 7,8-dihydroxyflavone derivative promotes neurogenesis and exhibits potent antidepressant effect

Doi:10.1021/jm101206p
(2010)
Stereochemistry of the three-component reaction between the ley′s aldehyde, benzyl amines, and trialkyl phosphites. a new approach to the protected enantiomerically pure 1-amino-2,3-dihydroxypropylphosphonates

Doi:10.1080/10426507.2014.883624
(2014)
Potassium thiocyanate-promoted one-pot synthesis of (1,3-diaryl-2,5- dioxoimidazolidin-4-ylidene)acetates from aryl isocyanates and alkyl propiolates short communication

Doi:10.1002/hlca.200900444
(2010)
Synthesis, characterisation and complexation of phosphino disilenes

Doi:10.1039/c0dt00180e
(2010)
N-Heterocyclic carbene stabilized adducts of alkyl magnesium amide, bisalkyl magnesium and Grignard reagents: Trapping oligomeric organo s-block fragments with NHCs

Doi:10.1039/c0dt00693a
(2010)
The imidazo[1,2-a]pyridine ring system as a scaffold for potent dual phosphoinositide-3-kinase (PI3K)/mammalian target of rapamycin (mTOR) inhibitors

Doi:10.1016/j.bmcl.2015.08.016
(2015)

Article Doi