Epoxidation Catalysed by Mn IIITPPCl using Dioxygen Activated by a System Containing N-Hydroxyphtalimide and Styrene, 2-Norbornene or Indene

DOI: 10.1039/P29890000951

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 951 - 956 (1989)

Update date:2022-07-29

Topics:

Authors:

Ozaki, Shigeko

Hamaguchi, Tomomi

Tsuchida, Keiichi

Kimata, Yukio

Masui, Masaichiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P29890000951

The catalytic epoxidation of alkenes by molecular oxygen activated in the system containing N-hydroxyphtalimide (NHPI) and active alkenes such as styrene, 2-norbornene or indene is reported.The transient intermediates, alkyl hydroperoxides formed by autooxidation of NHPI and the active alkenes are proposed as oxygen sources which transfer mono-oxygen to Mn^IIITPPCl.

Full text of DOI:10.1039/P29890000951

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:N-(3-hydroxyindan-2-yloxy)phtalimide

Cas No:125349-04-4

R&D Labs maybe for 125349-04-4

Zhejiang Sucon Silicone Co.,Ltd

Contact:+86-575-88046692

Address:Qisheng Rd., Paojiang Industrial Zone, Shaoxing, Zhejiang, China.
Wuxi Innopal International Trade CO.,LTD

Contact:+86-510-80711901-8003

Address:Room 402,Building 5,Longze Garden,No.17,South huanjiu Road,Yixing City, Jiangsu,China
Shanghai He Yang International Trading Co., Ltd.

Contact:+86-21-52043598

Address:Room 816, Blag.5, No.58 Huachi Road
Winchem Industrial Co. Ltd.(expird)

Contact:86-574-83851061 86-574-87083208

Address:Room 905, No.3 Building,East Business Center, 456 Xingning Road, Ningbo City,China
Taizhou Huading Chemical Co.,Ltd(expird)

Contact:+86-576-88583898

Address:Economic&Technology development zone,Taizhou City,Zhejiang Province,China

Relevant to this article

A synthetic 7,8-dihydroxyflavone derivative promotes neurogenesis and exhibits potent antidepressant effect

Doi:10.1021/jm101206p
(2010)
Stereochemistry of the three-component reaction between the ley′s aldehyde, benzyl amines, and trialkyl phosphites. a new approach to the protected enantiomerically pure 1-amino-2,3-dihydroxypropylphosphonates

Doi:10.1080/10426507.2014.883624
(2014)
Potassium thiocyanate-promoted one-pot synthesis of (1,3-diaryl-2,5- dioxoimidazolidin-4-ylidene)acetates from aryl isocyanates and alkyl propiolates short communication

Doi:10.1002/hlca.200900444
(2010)
Synthesis, characterisation and complexation of phosphino disilenes

Doi:10.1039/c0dt00180e
(2010)
N-Heterocyclic carbene stabilized adducts of alkyl magnesium amide, bisalkyl magnesium and Grignard reagents: Trapping oligomeric organo s-block fragments with NHCs

Doi:10.1039/c0dt00693a
(2010)
The imidazo[1,2-a]pyridine ring system as a scaffold for potent dual phosphoinositide-3-kinase (PI3K)/mammalian target of rapamycin (mTOR) inhibitors

Doi:10.1016/j.bmcl.2015.08.016
(2015)

Article Doi