Journal of the Chemical Society. Perkin transactions II p. 951 - 956 (1989)
Update date:2022-07-29
Topics:
Ozaki, Shigeko
Hamaguchi, Tomomi
Tsuchida, Keiichi
Kimata, Yukio
Masui, Masaichiro
The catalytic epoxidation of alkenes by molecular oxygen activated in the system containing N-hydroxyphtalimide (NHPI) and active alkenes such as styrene, 2-norbornene or indene is reported.The transient intermediates, alkyl hydroperoxides formed by autooxidation of NHPI and the active alkenes are proposed as oxygen sources which transfer mono-oxygen to MnIIITPPCl.
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