Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 2451 - 2456 (1991)
Update date:2022-08-04
Topics:
Rozhkov, I. N.
Chaplina, I. V.
Tertiary perfluoroalkyl bromides (RFBr) in nonpolar solvents under mild conditions can be added to the multiple bond of terminal alkenes, alkynes, and butadiene.Slow addition to alkenes at 20 deg C is accelerated in proton-donating solvents and is catalyzed by readily oxidizable nucleophiles.Bromination of the multiple bond and formation of RFBr reduction products suggests a radical-chain mechanism initiated by electron transfer to the RFBr molecule.
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