Journal of Organic Chemistry p. 2128 - 2132 (1990)
Update date:2022-07-29
Topics:
Hua, Duy H.
Bharati, S. Narashima
Robinson, Paul D.
Tsujimoto, Atsuko
α-Lithiated (+)-(R)-4,5-dihydro-2-<<(4-methylphenyl)sulfinyl>methyl>-3H-pyrrole (4) underwent annulation with 1,3-diiodopropane to give (-)-(S,S)-1,2,3,5,6,7-hexahydro-8-<(4-methylphenyl)sulfinyl>indolizine (6), which was converted into (-)-elaeokanine B (three steps) and (+)-elaeokanine A (four steps).
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