73. Synthesis of (+)-(4S,8R)-8-Epi- and (-)-(4R,8S)-4-Epi-β-bisabolol

DOI: 10.1002/hlca.19890720405

Source and publish data:

Helvetica Chimica Acta p. 653 - 658 (1989)

Update date:2022-09-26

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Authors:

Frater, Georg

Mueller, Urs

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Article abstract of DOI:10.1002/hlca.19890720405

The first total enantioselective synthesis of (+)-(4S,8R)-8-epi-β-bisabolol ((+)-1) and of (-)-(4R,8S)-4-epi-β-bisabolol ((-)-1) is reported.The key step in the synthesis is the kinetic resolution of (+-)-5 by means of the Sharpless epoxidation yielding (

Full text of DOI:10.1002/hlca.19890720405

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