Organometallics p. 1311 - 1314 (1990)
Update date:2022-08-04
Topics:
Nadeau, Fran?ois
Simard, Michel
Wuest, James D.
Neutralization of the mercuric oxide 1b with hexafluoroglutaric acid in 1,2-dimethoxyethane (DME) produces the 1:4 DME adduct of macrocyclic tetradentate Lewis acid 2b in 76% yield. An X-ray crystallographic study revealed that the macrocyclic host is approximately planar and that each 1,2-phenylenedimercury unit is associated with two molecules of DME, one above the plane and the other below. One oxygen atom from each molecule of DME bridges the two mercury atoms, and the other oxygen interacts with a single mercury. The resulting adduct is the first structurally characterized complex in which a basic guest and a multidentate Lewis acidic host share more than two bonds.
View MoreJintan Jinnuo Chemical Co., Ltd.
Contact:+86-519-80199901
Address:Room 1804, Building 1, Huacheng Business Plaza, Jintan, Jiangsu, China
Frapp's Chemical (NFTZ) Co.,Ltd
Contact:+86-576-86137892
Address:General Chamber of Commercial Building, 159 Wanchang Middle Road, Wenling, Zhejiang, China
HANGZHOU PANYU CHEMICAL CO.,LIMITED
Contact:+86-571-86578491
Address:Rm 605, NO.1870 Binsheng Road,Binjiang Dist, Hangzhou, China
Contact:86-574-26865651
Address:529 YuanBaoShan Road, Beilun District
Qingzhou Baibang import and export co.,Ltd
Contact:+86-536-3265899
Address:No.338, Tuoshan Road
Doi:10.1016/j.jfluchem.2007.07.016
(2007)Doi:10.1002/chem.201001754
(2010)Doi:10.1016/j.ejmech.2010.08.048
(2010)Doi:10.1039/c3sc51507a
(2013)Doi:10.1021/jacs.6b04935
(2016)Doi:10.1021/jo101769d
(2010)
