Matrix Reactions of Germane and Oxygen Atoms. Infrared Spectroscopic Evidence for Germylene-Water Complex, Germanone, Germanol, Hydroxygermylene, and Germanic Acid

DOI: 10.1021/j100369a030

Source and publish data:

Journal of Physical Chemistry p. 2351 - 2357 (1990)

Update date:2022-07-29

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Authors:

Withnall, Robert

Andrews, Lester

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Article abstract of DOI:10.1021/j100369a030

An extensive infrared study of the photochemical reaction of germane and ozone has been performed in solid argon.Isotopic substitution at all positions and filtered photolysis provide a basis for identification of seven new molecular product species.Germanone (H2GeO), the germylene-water complex (H2O-GeH2), and hydroxygermylene (HGeOH) appeared on red photolysis and gave way to germanic acid ((HO)2GeO), its peroxo isomer (H(O2)GeOH), germanium oxide (GeO), and germanol (H3GeOH) with ultraviolet photolysis.

Full text of DOI:10.1021/j100369a030

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