N-Substituted imidazole derivatives of rhodium(I) and iridium(I) with and without metal-metal interaction. Crystal structure of cis-(CO)2RhCl(N-methylimidazole)

DOI: 10.1016/0022-328X(89)88011-8

Source and publish data:

Journal of Organometallic Chemistry p. 253 - 266 (1989)

Update date:2022-07-29

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Authors:

Bonati, Flavio

Oro, Luis A.

Pinillos, M. Teresa

Tejel, Cristina

Apreda, M. Carmen

et al. et al.

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Article abstract of DOI:10.1016/0022-328X(89)88011-8

Bridge splitting reactions with N-methylimidazole (Rim, R=Me) or N-benzylimidazole (Rim, R=PhCH2) gave cis-L2MCl(Rim) complexes (M=Rh, Ir, L2=(CO)2, 1,5-cyclooctadiene; M=Rh, L2=(p-tosylmethyl isocyanide)2 or (CO)(PPh)3).M...M interactions in the dicarbon

Full text of DOI:10.1016/0022-328X(89)88011-8

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