Journal of the American Chemical Society p. 320 - 324 (1983)
Update date:2022-08-02
Topics:
Bays
Blumer
Baral-Tosh
Behar
Neta
A series of nitroaromatic compounds, containing Cl, Br or tosyl groups at various positions, were synthesized and studied by pulse radiolysis in aqueous alcohol solutions. One-electron reduction of the compounds produces the anion radicals which then undergo an intramolecular electron transfer and eliminate X** minus (Cl** minus , Br** minus , or TsO** minus ). The rates of X** minus elimination vary over six orders of magnitude and are affected by the C-X bond dissociation energies, the size and nature of the group bridging the X with the pi system, and the relative positions of these groups. Intramolecular electron transfer through space is also demonstrated. Refs.
View MoreContact:15973022782
Address:7-5-6218,Incubation Centre,Guandong Industry Park, East Lake High-Tech Development Zone,Wuhan City.
Shanghai He Yang International Trading Co., Ltd.
Contact:+86-21-52043598
Address:Room 816, Blag.5, No.58 Huachi Road
SHANDONG QINGYUNCHANGXIN CHEMICAL SCIENCE-TECH CO.,LTD
Contact:86-21-60560171
Address:1689Donghuan Rade,Qingyun County, Dezhou City, Shandong,China
Zhejiang Haizhou Pharmaceutical Co., Ltd.
website:https://www.haizhoupharma.com/
Contact:+86 576 88221016
Address:No. 19, Donghai 5th Avenue, Yanhai Industrial Zone, Linhai, Zhejiang, China
Zhushan County Tianxin Pharmaceutical & Chemical Co., Ltd.
Contact:0086-719-4224892
Address:Tutang Road, Chengguan Town, Zhushan County, Hubei Province
Doi:10.1039/c0ob00199f
(2010)Doi:10.1021/jo101776y
(2010)Doi:10.1021/ol102432q
(2010)Doi:10.1016/j.tet.2010.09.068
(2010)Doi:10.1134/S1070428010090216
(2010)Doi:10.1055/s-0030-1258186
(2010)