Design of structurally rigid trans -diamine-based Tf-amide organocatalysts with a dihydroanthracene framework for asymmetric conjugate additions of heterosubstituted aldehydes to vinyl sulfones

DOI: 10.1021/ja107897t

Source and publish data:

Journal of the American Chemical Society p. 17074 - 17076 (2010)

Update date:2022-07-30

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Authors:

Moteki, Shin A.

Xu, Senmiao

Arimitsu, Satoru

Maruoka, Keiji

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Article abstract of DOI:10.1021/ja107897t

Asymmetric conjugate addition of α-heterosubstituted aldehydes such as α-amido and α-alkoxy aldehydes to vinyl sulfone was effected under the influence of structurally rigid trans-diamine-based Tf-amido organocatalyst (S,S)-2 with a dihydroanthracene fram

Full text of DOI:10.1021/ja107897t

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