Allene/haloolefin electrocyclic reactions: A new route to stable triarylmethyl radicals

DOI: 10.1021/ja00162a050

Source and publish data:

Journal of the American Chemical Society p. 2402 - 2407 (1990)

Update date:2022-08-04

Topics:

Authors:

Porter, Ned A.

Hogenkamp, Derk J.

Khouri, Farid F.

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Article abstract of DOI:10.1021/ja00162a050

Electrocyclization of allene 1,1-diphenyl-3-[2-(2-bromoethenyl)phenyl]propadiene (5), followed by one-electron reduction with elemental mercury, gives β-naphthyldiphenylmethyl radical 6 in good yield. In the absence of mercury, the only product isolated i

Full text of DOI:10.1021/ja00162a050

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