Synthesis, structure, and reactivity of (phosphoranylidenephosphine)pentacarbonyltungsten complexes. Another access to the phosphorus-carbon double bond

DOI: 10.1021/ja00162a051

Source and publish data:

Journal of the American Chemical Society p. 2407 - 2410 (1990)

Update date:2022-08-04

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Authors:

Le Floch, Pascal

Marinetti, Angela

Ricard, Louis

Mathey, Fran?ois

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Article abstract of DOI:10.1021/ja00162a051

The reaction of trialkylphosphines with 7-phosphanorbornadiene PW(CO)₅ complexes affords the corresponding phosphoranylidenephosphine complexes R¹₃P=P(R)→W(CO)₅. One such complex (R = CO₂Et, R^{1
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Full text of DOI:10.1021/ja00162a051

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Product name:(2-(p-chlorophenyl)-1,4,5-trimethyl-1,2,3,6-tetrahydrophosphinine)pentacarbonyltungsten

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