An approach to the stereoselective synthesis of α-hydroxycarboxylic acids

DOI: 10.1016/0022-328X(87)80260-7

Source and publish data:

Journal of Organometallic Chemistry p. C29 - C33 (1987)

Update date:2022-09-26

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Authors:

Davies, Stephen G.

Wills, Martin

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Article abstract of DOI:10.1016/0022-328X(87)80260-7

The complex <(η⁵-C5H5)Fe(CO)(PPh3)COCH2OCH2Ph> undergoes, via the corresponding enolate, highly stereoselective alkylation, deuteration and aldol reactions, can be hydrogenated to the corresponding hydroxyacetyl complex, and gives the ester PhC

Full text of DOI:10.1016/0022-328X(87)80260-7

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