Facile Synthesis of SN and S-N-O Complexes in Liquid Ammonia; X-Ray Structure of Pt(PPh2Me)2

DOI: 10.1039/c39890001060

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1060 - 1061 (1989)

Update date:2022-07-30

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Authors:

Parkin, Ivan P.

Slawin, Alexandra M. Z.

Williams, David J.

Woollins, J. Derek

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Article abstract of DOI:10.1039/c39890001060

Addition of SCl2, SOCl2, SO2Cl2, or SeCl4 to liquid ammonia followed by Pt(PR3)2Cl2 gives complexes of the type Pt(S2N2)(PR3)2, Pt(NSO)2(PR3)2, Pt<(HN)2SO2>(PR3)2, and Pt(Se2N2)(PR3)2 respectively; the X-ray structure of Pt<(HN)2SO2>(PPh2Me)2 is reported.

Full text of DOI:10.1039/c39890001060

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