Multiple Bonds between Transition Metals and Main-Group Elements. 142. Lewis-Base Adducts of Organorhenium(VII) Oxides: Structures and Dynamic Behavior in Solution

Article abstract of DOI:10.1021/ic00115a019

Organorhenium(VII) oxides such as methyltrioxorhenium(VII) (1) and its longer-chain alkyl derivatives form 1:1 and 1:2 adducts with nitrogen-donor Lewis bases. These compounds adopt well-defined structures in the solid state. In solution, they undergo exc