Reaction of P-Halogeno-phospha-alkenes with Alkene Complexes of Nickel and Platinum: η2-Co-ordination and Unusual Oxidative Addition Behaviour

DOI: 10.1039/c39890001206

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1206 - 1207 (1989)

Update date:2022-08-02

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Authors:

Gudat, D.

Meidine, M. F.

Nixon, J. F.

Niecke, E.

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Article abstract of DOI:10.1039/c39890001206

Phospha-alkenes X-P=CTMS2 (X = F, Cl, I; TMS = SiMe3) display different reaction behaviour towards metal complexes (Bu3P)2Ni(cod) (cod = cyclo-octa-1,5-diene) or (PH3P)2Pt(C2H4), respectively, undergoing either co-ordination to give η²-phospha-

Full text of DOI:10.1039/c39890001206

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