ASYMMETRIC ALDOL REACTION OF Α-KETOESTERS WITH ISOCYANOACETATE AND ISOCYANOACETAMIDE CATALYZED BY A CHIRAL FERROCENYLPHOSPHINE-GOLD(I) COMPLEX

DOI: 10.1016/S0040-4039(01)80773-5

Source and publish data:

Tetrahedron Letters p. 4681 - 4684 (1989)

Update date:2022-08-06

Topics:

Authors:

Ito, Yoshihiko

Sawamura, Mayasa

Hamashima, Hitoshi

Emura, Takashi

Hayashi, Tamio

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Article abstract of DOI:10.1016/S0040-4039(01)80773-5

Asymmetric aldol reaction of α-ketoesters (RCOCOOMe: R=Me, i-Bu, Ph) with methyl isocyanoacetate or N,N-dimethyl-α-isocyanoacetamide in the presence of 1 molpercent of a chiral (aminoalkyl)ferrocenylphosphine-gold(I) catalyst proceeded with high enantiose

Full text of DOI:10.1016/S0040-4039(01)80773-5

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