SYNTHETIC STUDY TOWARDS THE TETRACYCLIC QUASSINOID SKELETON

DOI: 10.1016/S0040-4020(01)89783-0

Source and publish data:

Tetrahedron p. 2187 - 2194 (1990)

Update date:2022-08-05

Topics:

Authors:

Shing, Tony K. M.

Tang, Ying

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Article abstract of DOI:10.1016/S0040-4020(01)89783-0

The optically active tetracycle (6) with two trans-fused angular methyl groups is constructed from tiglic aldehyde and (S)-carvone in 9 steps involving a stereocontrolled aldol reaction and an endo-selective intramolecular Diels-Alder (IMDA) reaction.

Full text of DOI:10.1016/S0040-4020(01)89783-0

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