Unexpected Formation of 3,3,3-Trifluoropropyltriphenylphosphonium Bromide and Subsequent Wittig-Olefination

DOI: 10.1055/s-1989-27357

Source and publish data:

Synthesis p. 685 - 687 (1989)

Update date:2022-09-26

Topics:

Authors:

Ullmann, Joerg

Hanack, Michael

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1989-27357

An unusual rearrangement during the reaction of 1,1,1-trifluoroisopropyl bromide with triphenylphosphine leads to 3,3,3-trifluoropropyltriphenylphosphonium bromide, rendering the corresponding olefins accessible.

Full text of DOI:10.1055/s-1989-27357

Products guided by the article

Product name:(3,3,3-Trifluoro-propylidene)-cyclohexane

Cas No:126434-41-1

R&D Labs maybe for 126434-41-1

Taizhou YOJOY Chemical Co., Ltd.

Contact:13857143241

Address:Yangfu Industrial Park, Xianju, Zhejiang, P. R. China
Taimai Sanluck Pharmaceutical Co.,Ltd

Contact:86-592-7662921

Address:8D,No.186,Huarong Road,Huli,Xiamen,China
Changsha Yonta Industry Co., Ltd.

Contact:+ 86-731-8535 2228

Address:Rm.1717, North Bldg., No.368, East 2nd Ring Road(2nd Section)
Qingdao S. H. Huanyu Imp. & Exp. Co., Ltd.

Contact:86-532-88250866

Address:Room 615, World Trade Centre Building B, Hongkong Middle Roda 6#, Qingdao, Shandong, China
Tomo Pharma Chem Co., Limited

Contact:+86-158-05817090

Address:ROOM 9F, FLAT 2, GUODU DEVELOPING BLDG, No.182, ZHAOHUI ROAD

Relevant to this article

Copper-Catalyzed Modular Access to N-Fused Polycyclic Indoles and 5-Aroyl-pyrrol-2-ones via Intramolecular N—H/C—H Annulation with Alkynes: Scope and Mechanism Probes

Doi:10.1002/cjoc.202000246
(2020)
Synthesis and pharmacologic study of pyridazino[4,5-b]carbazoles

Doi:10.1248/cpb.37.2679
(1989)
Metal-1,10-Phenanthroline-Linked Dihydronicotinamides as Models for the NADH-Alcohol Dehydrogenase Coenzyme-Enzyme Couple

Doi:10.1021/jo00298a049
(1990)
Polymer complexes. LVIII. Structures of supramolecular assemblies of vanadium with chelating groups

Doi:10.1016/j.saa.2010.12.063
(2011)
Synthetic Approach to Pentaleno<2,1-b:5,4-b'>diindoles

Doi:10.1021/jo00299a031
(1990)
Stereocontrolled synthesis of 1,7a-diepialexine

Doi:10.1016/S0040-4039(00)92240-8
(1992)

Article Doi