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Asymmetric Aldol-type Reaction between Both Achiral Ketene Silyl Acetals and Aldehydes by the Use of a Chiral Promoter

DOI: 10.1246/cl.1989.1319

Source and publish data:

Chemistry Letters p. 1319 - 1322 (1989)

Update date:2022-09-26

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Authors:

Kobayashi, ShuKobayashi, Shu

Sano, TetsuyaSano, Tetsuya

Mukaiyama, TeruakiMukaiyama, Teruaki

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Article abstract of DOI:10.1246/cl.1989.1319

Highly enantioselective aldol-type reaction of achiral ketene silyl acetals with achiral aldehydes is carried out by the use of a chiral promoter, a combined use of chiral diamine coordinated tin(II) triflate and tributyltin fluoride.

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Full text of DOI:10.1246/cl.1989.1319

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