Electrophilic Additions of Positive Iodine to Alkynes through an Iodonium Mechanism

DOI: 10.1021/jo00297a027

Source and publish data:

Journal of Organic Chemistry p. 3104 - 3106 (1990)

Update date:2022-08-03

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Authors:

Barluenga, Jose

Rodriguez, Miguel A.

Campos, Pedro J.

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Article abstract of DOI:10.1021/jo00297a027

Alkynes react with bis(pyridine)iodonium (I) tetrafluoroborate (1) and nucleophiles (CH3COOH, HCOOH, Cl^-, pyridine, Br^-, I^-) to give 1,2 iodofunctionalized alkenes.The regiochemistry of the processes is in accordance with

Full text of DOI:10.1021/jo00297a027

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