Electrophilic Additions of Positive Iodine to Alkynes through an Iodonium Mechanism

DOI: 10.1021/jo00297a027

Source and publish data:

Journal of Organic Chemistry p. 3104 - 3106 (1990)

Update date:2022-08-03

Topics:

Authors:

Barluenga, Jose

Rodriguez, Miguel A.

Campos, Pedro J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00297a027

Alkynes react with bis(pyridine)iodonium (I) tetrafluoroborate (1) and nucleophiles (CH3COOH, HCOOH, Cl^-, pyridine, Br^-, I^-) to give 1,2 iodofunctionalized alkenes.The regiochemistry of the processes is in accordance with

Full text of DOI:10.1021/jo00297a027

Products guided by the article

Product name:(E)-(1-(formyloxy)-2-iodo-1-propenyl)benzene

Cas No:126501-64-2

R&D Labs maybe for 126501-64-2

Yangzhou Siyu Chemical Co.,Ltd.

Contact:+86-514-87325867 13358126196

Address:Room 620 Exposition Pavilion，No. 98 Huaihai Road,Guangling District，Yangzhou City, Jiangsu Province
Taizhou Sunny Chemical Co.,Ltd

Contact:+86-523-86920899 +86-13951172783

Address:No.11 Xingyuang road, Gaoyong Chemical Industry Park, Gaogang Jiangsu China
SHANDONG AONA CHEMICAL CO.,LTD.

Contact:86-532-85762926

Address:LIUYUAN TOWN, ZAOZHUANG CITY, SHANGDONG PROVINCE.
Shanghai Cheerchem Co., Ltd.

Contact:86-21-50966856

Address:Building 5,300 Chuanzhan Road,Pudong New District,Shanghai
Greenutra Resource Inc

website:http://www.greenutra.cn

Contact:0086-411-39553357

Address:No. 7-1-1802, Huizhi Garden,Ocean Square,Dalian, 116033, China

Relevant to this article

Modular amino acids and β-amino alcohol-based chiral ligands for enantioselective addition of diethylzinc to aromatic aldehydes

Doi:10.1002/aoc.1724
(2011)
Chemical synthesis of site-specifically 2'-azido-modified RNA and potential applications for bioconjugation and RNA interference

Doi:10.1002/cbic.201000646
(2011)
Photochemical formation of thiirene and thioketene in 1,2,3-thiadiazoles with phenyl substituents studied by time-resolved spectroscopy

Doi:10.1039/c3pp25453d
(2013)
Doi:10.1021/ja01628a069
(1955)
Doi:10.1021/ja01640a017
(1954)
Synthesis of condensed heteroaromatics: Novel synthesis of aminoquinolizinone derivatives as anti-HIV agents

Doi:10.1016/S0040-4020(01)01039-0
(2001)

Article Doi