A SYNTHESIS OF (-)-DEOXYPODOCARPIC ACID METHYL ESTER VIA AN ENZYMATIC ENANTIOSELECTIVE HYDROLYSIS OF THE KEY INTERMEDIATE ENOL ESTER

DOI: 10.1016/S0040-4020(01)85126-7

Source and publish data:

Tetrahedron p. 6135 - 6144 (1989)

Update date:2022-09-26

Topics:

Authors:

Sugai, Takeshi

Kakeya, Hideaki

Ohta, Hiromichi

Morooka, Mitsuo

Ohba, Shigeru

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Article abstract of DOI:10.1016/S0040-4020(01)85126-7

(1R,4aR,10aS)-(-)-1-Methoxycarbonyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthrene (deoxypodocarpic acid methyl ester 1), a useful intermediate for the synthesis of various diterpenes, was synthesized from (R)-(+)-6-ethoxycarbonyl-2,6-dimethyl-1-

Full text of DOI:10.1016/S0040-4020(01)85126-7

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