Tetrahedron Letters p. 3789 - 3792 (1989)
Update date:2022-08-02
Topics:
Satoh, Makoto
Nomoto, Yoshihiro
Miyaura, Norio
Suzuki, Akira
Hydroboration of 1,3-butadiene, isoprene, myrcene, 2,3-dimethyl-1,3-butadiene, and 1,3-cyclohexadiene with catecholborane(1,3,2-benzodioxaborole) in the presence of Pd(PPh3)4 or Rh4(CO)12 catalysts proceeds smoothly to provide 2-<(Z)-2-alkyl-2-butenyl>-1,3,2-benzodioxaboroles in very high regio- and stereoselectivity.
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