Synthesis and Structure of a Bridged Twelve-membered Silver-Zinc-Sulfur Cyclic Compound: a Combination of Hard and Soft Lewis Acidic and Basic Centers

DOI: 10.1039/c39920000689

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 689 - 690 (1992)

Update date:2022-07-29

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Authors:

Steiner, Matthias

Gruetzmacher, Hansjoerg

Zolnai, Laszlo

Huttner, Gottfried

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Article abstract of DOI:10.1039/c39920000689

The reaction of silver trifluoromethanesulfonate 2 with zinc bis 4 and 2,4,6-triisopropylbenzenethiol 5 in a 4:4:6 ratio yields the mixed metal thiolate complex 3 with a twelve-membered silver-zinc-sulfur ring bridged by two trifluoromethanesulfonate anions; compound 3 is remarkably stable in solution.

Full text of DOI:10.1039/c39920000689

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