Journal of the Chemical Society. Chemical communications p. 1442 - 1445 (1989)
Update date:2022-08-05
Topics:
Yu, Kuo-Long
Fraser-Reid, Bert
The enolate of the 2-deoxy-3-oxo-pyranoside (1) undergoes aldol additions from the β-face exclusively, and so stereoselectivity of the reaction apparently relies entirely on control elements in the aldehyde, such as α- or α,β-chelation.
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