CARBO- AND HETEROCYCLIZATION REACTIONS OF 2-(4-MORPHOLINYL)-1-PHENYLPROPENE AND NITROOLEFINS

DOI: 10.1016/S0040-4020(01)89509-0

Source and publish data:

Tetrahedron p. 5667 - 5678 (1989)

Update date:2022-08-03

Topics: Reduction of Nitro Group Hetero-Diels-Alder Reaction [4+2] Cycloaddition

Authors:

Felluga, F.

Nitti, P.

Pitacco, G.

Valentin, E.

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Article abstract of DOI:10.1016/S0040-4020(01)89509-0

The title enamine may exist in two double bond isomers.Both forms react with the nitroolefins under different conditions to afford, after hydrolysis, regioisomeric γ-nitroketones. γ-Dicarbonyl compounds are isolated from the hydrolysis at pH 2 of the 1,2-oxazine N-oxide systems, which in some cases have also been separated.

Full text of DOI:10.1016/S0040-4020(01)89509-0

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