Angewandte Chemie - International Edition p. 15787 - 15791 (2016)
Update date:2022-09-26
Topics:
Komiyama, Takeshi
Minami, Yasunori
Hiyama, Tamejiro
Aryl(triethyl)silanes are found to undergo cross-coupling with iodoarenes in the presence of catalytic amounts of CuBr2and Ph-Davephos, as well as cesium fluoride as a stoichiometric base. Because the silicon reagents are readily accessible through catalytic C?H silylation of aromatic substrates, the net transformation allows coupling of aromatic hydrocarbons with iodoarenes via triethylsilylation.
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