Tetrahedron p. 555 - 562 (1991)
Update date:2022-08-04
Topics:
Uneyama, Kenji
Trifluoroacetic acid (TFA) can be converted almost quantitatively to the trifluoromethyl radicals by electrochemical oxidation of TFA.The electrolysis is conducted in an MeCN-H2O-(Pt) system using an undivided cell.The electrochemically generated CF3. radicals can attack mostly electron-deficient olefins leading to the trifluoromethylated carbon radicals of which chemical and electrochemical fate can be controlled by current density, reaction temperature, and substituents of olefins.
View MoreJiangxi Province Bethel Pharmaceutical Co., Ltd.
Contact:+86-795-259 3456 ，+86-15957688008 13566650571
Address:Huangjindui Chemical Park， Shanggao County ，Yichun city，Jiangxi Province
Hangzhou Eastbiopharm Co.,Ltd.
Contact:+86-571-88931780
Address:Hangzhou,China
Contact:0091-265-2313036
Address:311, ATLANTIS HEIGHTS SARABHAI MAIN ROAD,VADIWADI ,VADODARA
NINGBO YINLIANG FOREIGN TRADE CO., LTD.
Contact:+86-574-87834016 / 87898057
Address:23F NO.666JINYU ROAD,YINGZHOU DISTRICT,NINGBO.CHINA
Zhejiang Allied Chemical Co.,Ltd
Contact:18967038207
Address:Area A-30, High-tech Industrial Park, Quzhou, Zhejiang, China.
Doi:10.1039/b414739a
(2005)Doi:10.1021/jm101165z
(2011)Doi:10.1021/ja00096a056
(1994)Doi:10.1016/S0957-4166(98)00172-4
(1998)Doi:10.1016/S0040-4039(97)00472-3
(1997)Doi:10.1021/om961072v
(1997)
