O-N, S-N AND N-N EXCHANGE REACTIONS AT OLEFINIC CARBON ATOMS: FACILE SYNTHETIC METHOD FOR β-TRIFLUOROACETYLVINYLAMINES

DOI: 10.1016/S0040-4039(01)93334-9

Source and publish data:

Tetrahedron Letters p. 6173 - 6176 (1989)

Update date:2022-08-05

Topics:

Authors:

Hojo, Masaru

Masuda, Ryoichi

Okada, Etsuji

Sakaguchi, Syuhei

Narumiya, Hitoshi

Morimoto, Katsushi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)93334-9

β-Trifluoroacetylvinyl ethers 1 and sulfides 2 react easily with various amines at room temperature to give β-trifluoroacetylvinylamines 3 in excellent yields.This O-N and S-N exchange reaction can be extended to N-N exchange reaction.

Full text of DOI:10.1016/S0040-4039(01)93334-9

Products guided by the article

Product name:3-Buten-2-one, 1,1,1-trifluoro-4-[(4-methoxyphenyl)amino]-, (3Z)-

Cas No:127223-91-0

R&D Labs maybe for 127223-91-0

Liaoyang hengye Chemical Co., Ltd.

Contact:86-419-5850866

Address:North Old Xiaoxiao Road,Yantai District, Dengta, Liaoyang, Liaoning, China
Shandong Xiangde Biotechnology Co., Ltd

Contact:+86 -15066639877

Address:Sanba street
Shenzhen Feiming Science and Technology Co,. Ltd

Contact:+86-755-85232577

Address:#B2309, Fenglin International Center ,Jixiang Road, Longcheng street, LongGang District, Shenzhen city, Guangdong province, China.
Chongqing Werlchem Fine Chemical Co. Ltd

Contact:+86-23-67521957

Address:NO.15,Fortune Road,Yubei District,401121,Chongqing,China
JIANGXI AIFEIMU TECHNOLOGY CO.，LTD

Contact:+86-570-6040289

Address:FINECHEMICAL PARK,ZIBU TOWN,WANNIAN COUNTY,JIANGXI PROV.,CHINA,ZIP

Relevant to this article

New analogues of (E)-β-farnesene with insecticidal activity and binding affinity to aphid odorant-binding proteins

Doi:10.1021/jf104712c
(2011)
General Synthesis of β,γ-Alkynylglycine Derivatives

Doi:10.1021/jo00302a034
(1990)
THE NITRATION OF p-CYMENE WITH NITROGEN DIOXIDE IN ACETIC ANHYDRIDE: THE ISOLATION AND X-RAY STRUCTURE DETERMINATION OF 6-METHYL-3-(METHYLETHYL)-t-5-NITRATO-1,r-3,c-4,t-6-TETRANITROCYCLOHEXENE

Doi:10.1016/S0040-4039(00)82101-2
(1988)
Remarkable influence of the cyclometalating ligand on the nuclearity and properties of heterobridged (μ-X)(μ-C=CR) platinum(II) complexes

Doi:10.1021/om101172p
(2011)
Synthesis of gold complexes bearing sterically highly encumbered, chiral carbene ligands

Doi:10.1021/om101192k
(2011)
NIR-emitting styryl dyes with large Stokes’ shifts for imaging application: From cellular plasma membrane, mitochondria to zebrafish neuromast

Doi:10.1016/j.dyepig.2021.109629
(2021)

Article Doi