Selenium-Catalyzed Conversion of Methyl Ketones into α-Keto Acetals

DOI: 10.1021/jo00302a012

Source and publish data:

Journal of Organic Chemistry p. 4523 - 4528 (1990)

Update date:2022-09-26

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Authors:

Tiecco, M.

Testaferri, L.

Tingoli, M.

Bartoli, D.

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Article abstract of DOI:10.1021/jo00302a012

The reaction of methyl ketones with catalytic amounts of diphenyl diselenide and an excess of ammonium peroxydisulfate in methanol proceeds smoothly to afford α-keto acetals in good yield.In some cases reaction yields were increased by using stoichiometri

Full text of DOI:10.1021/jo00302a012

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