Selenium-Catalyzed Conversion of Methyl Ketones into α-Keto Acetals

DOI: 10.1021/jo00302a012

Source and publish data:

Journal of Organic Chemistry p. 4523 - 4528 (1990)

Update date:2022-09-26

Topics:

Authors:

Tiecco, M.

Testaferri, L.

Tingoli, M.

Bartoli, D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00302a012

The reaction of methyl ketones with catalytic amounts of diphenyl diselenide and an excess of ammonium peroxydisulfate in methanol proceeds smoothly to afford α-keto acetals in good yield.In some cases reaction yields were increased by using stoichiometri

Full text of DOI:10.1021/jo00302a012

Products guided by the article

Product name:1-(1-cyclohexenyl)-2,2-dimethoxyethanone

Cas No:127256-02-4

R&D Labs maybe for 127256-02-4

Pale Palm Imex

Contact:+36(21)2523420

Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA
Innua Petrochem Ltd.

Contact:+1-284-4950244

Address:Box 3069, Road Town, Tortola, British Virgin Islands
CE Pharm Co.,Ltd

Contact:+86 15317222985

Address:Zhejiang
Tengzhou Runlong Fragrance Co., Ltd.

website:http://www.tzrunlong.com/

Contact:--

Address:No. 78, Fushan Road, Biomedical Industrial Park, Dawu Town, Tengzhou, Shandong, 277514 China
Quzhou Ruiyuan chemical Co., Ltd

Contact:+86-570-3039321/3039361/3039308

Address:18# Huayang Road,Quzhou High-tech Industrial Park, Zhejiang China.

Relevant to this article

Enabling the development of N-Heterocyclic Carbene (NHC) catalyzed reactions: Practical methods for the preparation of 1-acyl-2-alkylcycloalkenes from cycloalkanones

Doi:10.1071/CH11183
(2011)
Synthesis of MUC1 Neoglycopeptides using efficient microwave-enhanced chaotrope-assisted click chemistry

Doi:10.1039/c0ob01043j
(2011)
Design, synthesis and evaluation of a chiral propranolol selector

Doi:10.1016/0957-4166(96)00337-0
(1996)
Resolution of a CBI precursor and incorporation into the synthesis of (+)-CBI, (+)-CBI-CDPI₁, (+)-CBI-CDPI₂: Enhanced functional analogs of (+)-CC-1065. A critical appraisal of a proposed relationship between electrophile reactivity,

Doi:10.1016/S0040-4039(00)94629-X
(1990)
Comparison of imine to olefin insertion reactions: Generation of five- and six-membered lactams via a nickel-mediated co, olefin, co, imine insertion cascade

Doi:10.1021/om1011566
(2011)
Driving catalyst reoxidation in wacker cyclizations with acetal-based metal-hydride abstractors

Doi:10.1021/om2001958
(2011)

Article Doi