DIRECTIVE EFFECTS IN HYDROBORATIONS OF 1-(TRIALKYLSILYL)-1,3-DIYNES. SYNTHESES OF (Z)-ENYNES AND α-KETOACETYLENES

DOI: 10.1016/S0040-4039(01)89001-8

Source and publish data:

Tetrahedron Letters p. 6487 - 6490 (1989)

Update date:2022-08-05

Topics:

Authors:

Stracker, Elaine C.

Leong, William

Miller, Joseph A.

Shoup, Timothy M.

Zweifel, George

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)89001-8

Chemo- and regioselective hydroborations of 1-(dimethylthexylsilyl)-1,3-diynes with dicyclohexylborane or with furnishes organoboranes which afford on protonation (Z)-enynes and on oxidation alkynyl ketones.

Full text of DOI:10.1016/S0040-4039(01)89001-8

Products guided by the article

Product name:1-Cyclohexyl-4-[dimethyl-(1,1,2-trimethyl-propyl)-silanyl]-but-3-yn-2-one

Cas No:127286-73-1

R&D Labs maybe for 127286-73-1

Shandong Bolode Bio-Technology Co., LTD

Contact:+86-0531-58966870

Address:136 Jingyi Road,Huaiyin District,Jinan,Shandong,China
Shenyang NovPharm Technology Co., Ltd.

Contact:.+86-24-24165786

Address:Room 306, Hongjin Mansion, No. 36-1, Wanliutang Rd., Shenhe District, Shenyang, Liaoning, P.R.C.
shijiazhuang alkay chemicals co..ltd(expird)

Contact:86-311-67692035

Address:2601,juntang building,qiaodong district,shijiazhuang
NEM CHEMICAL CO.，LTD

website:http://www.NEM.COM.CN

Contact:+86-393-4411771

Address:The west section of shengli Road,Puyang,Henan Province,China
TIANJIN GST CHEMICAL TECHNOLOGY CO., LTD

Contact:+86-22-25210964

Address:Room. 208, No. -12-C, No. 13, Xinbei Road, Tanggu District, New Haixin Area, Tianjin City, China

Relevant to this article

Anionic activators for differential sensing with cell-penetrating peptides

Doi:10.1002/asia.201000700
(2011)
An Air-Stable Dimeric Ru-S Complex with an NHC as Ancillary Ligand for Cooperative Si-H Bond Activation

Doi:10.1021/acs.organomet.6b00110
(2016)
Cholecystokinin antagonists: (R)-tryptophan-based hybrid antagonists of high affinity and selectivity for CCK-A receptors

Doi:10.1021/jm00116a002
(1991)
Installation/modulation of the emission response via click reaction

Doi:10.1021/jo200231k
(2011)
Nuclease p1: A new biocatalyst for direct asymmetric aldol reaction under solvent-free conditions

Doi:10.1039/c0gc00486c
(2011)
Studies on Neurokinin Antagonists. 2. Design and Structure-Activity Relationships of Novel Tripeptide Substance P Antagonists, N^α-α-(N^α-Acetyl-L-threonyl)-N¹-formyl-D-tryptophyl>-N-methyl-N-(phenylmethyl)-L-ph

Doi:10.1021/jm00095a013
(1992)

Article Doi