A NEW GENERAL SYNTHESIS OF SULFONES FROM ALKYL OR ARYL HALIDES AND p-TOLUENESULFONHYDRAZIDE

DOI: 10.1016/S0040-4020(01)89148-1

Source and publish data:

Tetrahedron p. 6791 - 6798 (1989)

Update date:2022-07-29

Topics:

Authors:

Ballini, Roberto

Marcantoni, Enrico

Petrini, Marino

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)89148-1

Here we report the utilization of commercially available p-toluenesulfonhydrazide as a new nucleophilic reagent in displacement reactions with suitable halides for an improved, general synthesis of sulfones.Good results are obtained with primary, secondary, allylic, benzylic, and aromatic halides activated by withdrawing groups.

Full text of DOI:10.1016/S0040-4020(01)89148-1

Products guided by the article

Product name:3,4-dinitro-1-(4-methylphenylsulfonyl)-benzene

Cas No:127291-62-7

R&D Labs maybe for 127291-62-7

VanderArk International Limited

Contact:86-10-82437576

Address:Qing He
Zhengzhou Minzhong Pharmaceutical Co.,ltd

Contact:0086-371-65797115

Address:15/F,Jiangshan Bldg, NO.126 Huanghe Road,Zhengzhou, China
JiYi Chemical (Beijing) Co., Ltd.

Contact:+86-10-89385733

Address:Shilou Town of Fangshan District， Beijing
Zhejiang Kaili Industrial Co., Ltd

Contact:+86-571-85241926

Address:lantian business center,No.18 Moganshan Road
NANCHANG QINZHI SCI&TEC.CO.,LTD(expird)

Contact:+86-13687004106

Address:Hero South Road,Hero Zone,Nanchang,Jiangxi,China

Relevant to this article

Phosphorus-carbon bond formation: Palladium-catalyzed cross-coupling of H-phosphinates and other P(O)H-containing compounds

Doi:10.1002/adsc.201300069
(2013)
Enantiospecific total synthesis of a novel arachidonic acid metabolite 3-hydroxyeicosatetraenoic acid

Doi:10.1016/S0040-4039(97)10565-2
(1998)
C5-functionalized DNA, LNA, and α- L -LNA: Positional control of polarity-sensitive fluorophores leads to improved SNP-Typing

Doi:10.1002/chem.201002109
(2011)
Dehydrogenative C(sp³)-H bond functionalization of tetrahydroisoquinolines mediated by organic oxidants under mild conditions

Doi:10.1039/c9ob01090d
(2019)
Enantioselective Synthesis of Cyclic Nitrones by Chemoselective Intramolecular Allylic Alkylation of Oximes

Doi:10.1002/anie.202100150
(2021)
Synthesis of &β-Methoxy Enones via a New Two-Carbon Extension of Carboxylic Acids

Doi:10.1021/jo00302a056
(1990)

Article Doi