Stereoselective 1,3-Dipolar Cycloadditions of Photochemically Generated Azomethine Ylides to Oppolzer's Chiral Acryloyl Sultam. An Asymmetric Approach to Quinocarcin

DOI: 10.1021/jo00300a004

Source and publish data:

Journal of Organic Chemistry p. 3973 - 3975 (1990)

Update date:2022-07-29

Topics:

Authors:

Garner, Philip

Ho, Wen Bin

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00300a004

Photochemically generated azomethine ylides undergo highly stereoselective 1,3-dipolar cycloadditions (ds >25:1) to chiral acryloyl sultams to give the substituted 3,8-diazabicyclo<3.2.1>octane moiety of quinocarcin.

Full text of DOI:10.1021/jo00300a004

Products guided by the article

Product name:Acetic acid (S)-2-[(1R,5S,6R)-6-((1R,5S,7S)-10,10-dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]decane-4-carbonyl)-8-methyl-2,4-dioxo-3,8-diaza-bicyclo[3.2.1]oct-3-yl]-2-phenyl-ethyl ester

Cas No:127381-63-9

R&D Labs maybe for 127381-63-9

Shanghai PuYi Chem-Tech Co.,Ltd.

Contact:+86-21-57687505-227

Address:3 Floor, Building 11, No 201 MinYi Road, Songjiang District, Shanghai 201612, China
Shanghai birch chemical technology co.,ltd

Contact:+86-21-54096810

Address:No.2588,Jungong Road,Shanghai,China
nanjing suru chemical co.ltd

Contact:+86-025-52406782

Address:8 Taizishan Rd., Yanjiang Industrial Development Area, Nanjing, Jiangsu, China.
Shanghai united Scientific Co.,Ltd.

Contact:+86-21-53535353

Address:28F No.900 huaihai Road Shanghai China
ZCIC INTERNATIONAL LTD

Contact:+86-512-56795332

Address:No227 Shuanglong Rd, Fenghuang, Zhangjiagang

Relevant to this article

2-(Fluoro-) and 2-(methoxyanilino)-1,4-naphthoquinones. Synthesis and mechanism and effect of fluorine substitution on redox reactivity and NMR

Doi:10.1016/j.jfluchem.2015.08.016
(2015)
A practical optical resolution of (arylsulfinyl)acetones and its application to the synthesis of 2-(arylsulfinyl)cycloalkanones

Doi:10.1246/bcsj.62.3531
(1989)
A new synthetic route to P-chiral phosphine-boranes of high enantiopurity via stereocontrolled Pd(0)-Cu(I) cocatalyzed aromatic phosphorylation

Doi:10.1021/jo0003605
(2000)
Diastereoselection in reactions of pinanediol dichloromethaneboronate

Doi:10.1021/om50005a010
(1983)
Generation and Reactions of the Dianion of 3-Hydroxy-5-methylisoxazole, a Covenient β-Keto Amide Sython. Total Synthesis of Muscimol

Doi:10.1021/jo00171a030
(1983)
Doi:10.1021/ja01852a037
(1941)

Article Doi