Stereoselective 1,3-Dipolar Cycloadditions of Photochemically Generated Azomethine Ylides to Oppolzer's Chiral Acryloyl Sultam. An Asymmetric Approach to Quinocarcin

DOI: 10.1021/jo00300a004

Source and publish data:

Journal of Organic Chemistry p. 3973 - 3975 (1990)

Update date:2022-07-29

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Authors:

Garner, Philip

Ho, Wen Bin

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Article abstract of DOI:10.1021/jo00300a004

Photochemically generated azomethine ylides undergo highly stereoselective 1,3-dipolar cycloadditions (ds >25:1) to chiral acryloyl sultams to give the substituted 3,8-diazabicyclo<3.2.1>octane moiety of quinocarcin.

Full text of DOI:10.1021/jo00300a004

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