Palladium(II)-catalyzed c-h bond arylation of electron-deficient arenes at room temperature

DOI: 10.1002/anie.201005990

Source and publish data:

Angewandte Chemie - International Edition p. 1076 - 1079 (2011)

Update date:2022-08-04

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Authors:

Tredwell, Matthew J.

Gulias, Moises

Gaunt Bremeyer, Nadine

Johansson, Carin C. C.

Collins, Beatrice S. L.

Gaunt, Matthew J.

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Article abstract of DOI:10.1002/anie.201005990

Mild and tolerant: A novel Pd^II-catalyzed C-H bond arylation with aryl-BF₃K salts transforms various electron-deficient arenes under mild reaction conditions. Benzaldehydes are functionalized in the ortho position using a temporary imine directing group that controls the cyclopalladation. A broad range of benzaldimines are compatible with this process (see scheme).

Full text of DOI:10.1002/anie.201005990

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