α',α'-DISILYLATED TERTIARY BENZAMIDES AS DUAL ORTHO- AND α'-CARBANION SYNTHONS. AMIDE PETERSON OLEFINATION ROUTES TO N-BENZOYL ENAMINES, ISOQUINOLINES, AND DIBENZAZOCINES

DOI: 10.1016/S0040-4039(01)93485-9

Source and publish data:

Tetrahedron Letters p. 5841 - 5844 (1989)

Update date:2022-08-04

Topics:

Authors:

Cuevas, J.-C.

Patil, P.

Snieckus, V.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)93485-9

α',α'-Disilylated benzamides 2, prepared by LiTMP/TMSCl in situ trap procedure, constitute ortho- and α'-carbanion synthons which provide N-benzoyl enamines (5), isoquinolines (6), dibenzoazocines (9) by Peterson olefination, and pyrroles (11) by cycloaddition.The conversion of 2 into other useful functionality is described.

Full text of DOI:10.1016/S0040-4039(01)93485-9

Products guided by the article

Product name:4-hydroxy-2-methyl-3,4-dihydroisoquinolin-1(2H)-one

Cas No:127787-23-9

R&D Labs maybe for 127787-23-9

Shaanxi King Stone Enterprise Company Limited

Contact:86-29-88353805,13609285751

Address:.209 Keji Road Hi-Tech industrial Develpment Zone .Xian China
Xiamen XM-Innovation Chemical Co., Ltd

Contact:+86-592-3216205

Address:Unit Q, 11/F, No.1 Office Building, Wuyuan Bay Business Center, Huli District, Xiamen City, Fujian Province, P.R.C
Wuhan Newgreat Chemical Co., Ltd

website:http://www.newgreat.cn

Contact:86-027-85953558

Address:East Lake high tech Development Zone, Wuhan, 262, No.
Tianjin Derchemist Sci-Tech Co., Ltd.

website:http://www.derchemist.com

Contact:+86-22-58627059

Address:Xinmao Science and Technology Park，Huayuan Industrial Park
Zibo Ocean International Trade Co.,Ltd(expird)

Contact:+86 533 5160706

Address:1117, Hongtai Bld., Songling rd, Zichuan,Zibo,Shandong,China

Relevant to this article

The cysteine 703 to isoleucine or histidine mutation of the oxidosqualene-lanosterol cyclase from Saccharomyces cerevisiae generates an iridal-type triterpenoid

Doi:10.1016/j.biochi.2012.06.014
(2012)
Synthesis and biological evaluation of 2-aminoimidazole/carbamate hybrid anti-biofilm and anti-microbial agents

Doi:10.1016/j.bmcl.2010.12.057
(2011)
Heteroleptic organostannylenes and an organoplumbylene bearing phosphorus-containing pincer-type ligands - Structural variations and insights into the configurational stability

Doi:10.1002/zaac.201000387
(2011)
Synthesis, electronic structure, and catalytic activity of reduced bis(aldimino)pyridine iron compounds: Experimental evidence for ligand participation

Doi:10.1021/ic102186q
(2011)
Studies on 3-oxoalkanenitriles: Novel rearrangement reactions observed in studies of the chemistry of 3-heteroaroyl-3-oxoalkanenitriles as novel routes to 2-dialkylaminopyridines

Doi:10.3390/molecules17010897
(2012)
A high yielding, one-pot synthesis of S,S-dialkyl dithiocarbonates through the corresponding thiols using Mitsunobu's reagent

Doi:10.1007/BF03246060
(2010)

Article Doi