Tetrahedron Letters p. 5841 - 5844 (1989)
Update date:2022-08-04
Topics:
Cuevas, J.-C.
Patil, P.
Snieckus, V.
α',α'-Disilylated benzamides 2, prepared by LiTMP/TMSCl in situ trap procedure, constitute ortho- and α'-carbanion synthons which provide N-benzoyl enamines (5), isoquinolines (6), dibenzoazocines (9) by Peterson olefination, and pyrroles (11) by cycloaddition.The conversion of 2 into other useful functionality is described.
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