Synthesis and Crystal and Molecular Structure of the Conformationally Restricted Methionine Analogue. (+/-)-2-exo-Amino-6-endo-(methylthio)bicycloheptane-2-endo-carboxylic Acid and Neighboring Group Participation in Its Anodic Oxidation

DOI: 10.1021/jo00299a020

Source and publish data:

Journal of Organic Chemistry p. 3797 - 3804 (1990)

Update date:2022-08-02

Topics:

Authors:

Glass, Richard S.

Hojjatie, Massoud

Sabahi, Mahmood

Steffen, L. Kraig

Wilson, George S.

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Article abstract of DOI:10.1021/jo00299a020

(+/-)-2-exo-Amino-6-endo-(methylthio)bicyclo<2.2.1>heptane-2-endo-carboxylic acid (1c) was synthesized by amination of the lithium enolate of methyl 6-endo-(methylthio)bicyclo<2.2.1>heptane-2-endo-carboxylate with O-(mesitylensulfonyl)hydroxylamine follow

Full text of DOI:10.1021/jo00299a020

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