
Tetrahedron p. 433 - 444 (1990)
Update date:2022-07-29
Topics:
Bertho
Robert
Batail
Robin
4-Thioxo mesoionic dithioles substituted at the position five by a R1 lipophilic group or by a R1 hydrophilic group, are obtained from gem dicyano epoxides. Their alcoylation with an hydrophilic (or potentialy hydrophilic) R2X derivative, or with a lipophilic R2X derivative, followed by a reduction, gives rise to amphiphilic dithioles which are the precursors of the amphiphilic tetrathiafulvalenes.
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(2011)