Synthesis and functionalisation of intermediates derived from allylmagnesiation of (E)-1-(trimethylsilyl)-but-1-en-3-ol

DOI: 10.1016/S0040-4039(00)70668-X

Source and publish data:

Tetrahedron Letters p. 6753 - 6756 (1989)

Update date:2022-07-31

Topics:

Authors:

Kocienski

Love Love

Roberts Roberts

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Article abstract of DOI:10.1016/S0040-4039(00)70668-X

Allylmagnesium bromide adds to (E)-1-(trimethylsilyl)-but-1-en-3-ol diastereoselectively. The carbon-magnesium bond of the intermediate adducts reacts with a range of electrophiles to give synthetically useful products.

Full text of DOI:10.1016/S0040-4039(00)70668-X

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