Synthesis and functionalisation of intermediates derived from allylmagnesiation of (E)-1-(trimethylsilyl)-but-1-en-3-ol

DOI: 10.1016/S0040-4039(00)70668-X

Source and publish data:

Tetrahedron Letters p. 6753 - 6756 (1989)

Update date:2022-07-31

Topics:

Authors:

Kocienski

Love Love

Roberts Roberts

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)70668-X

Allylmagnesium bromide adds to (E)-1-(trimethylsilyl)-but-1-en-3-ol diastereoselectively. The carbon-magnesium bond of the intermediate adducts reacts with a range of electrophiles to give synthetically useful products.

Full text of DOI:10.1016/S0040-4039(00)70668-X

Products guided by the article

Product name:(1R,2R,3S,4S)-3-Allyl-1-phenyl-2-trimethylsilanyl-pentane-1,4-diol

Cas No:127781-03-7

R&D Labs maybe for 127781-03-7

ZHEJIANG JIANYE CHEMICAL CO.,LTD.

Contact:86-571-64149273,64149234

Address:No. 48, Fuxi Road, Meicheng Town
Puyang Huicheng Electronic Material Co., Ltd

website:http://huichengchem.weba.testwebsite.cn/index_en.html

Contact:+86-393-8910800

Address:West Section Shengli Road, Puyang457000, China
Shanghai Demand Chemical Co., ltd，China

Contact:86-021-55237578/55239122

Address:Room 3H, No.578, Yingkou Road, Yangpu District, Shanghai, China
Chengdu Herbpurify Co., Ltd

website:http://www.herbpurify.com

Contact:0086-028-85249238

Address:Room709-C1,Incubator Building, Tianfu Life Science Park No.88,Keyuan Road,Gaoxin district,Chengdu City,Sichuan Prov,China
Shenyang Xinyihan Chemical Technology Co., Ltd.

Contact:+86-18525026267

Address:362, aigongbeijei street 23 , tiexi district,Shenyang, Liaoning, China

Relevant to this article

CONDENSED IMIDAZO-1,2,4-AZINES. 22. ALKYLATION OF 5H-IMIDAZO<1,2-b>-1,2,4-TRIAZEPIN-4-ONES

Doi:10.1007/BF00499416
(1990)
Selective reduction of 2,4-dinitro- and 4,5-dinitroimidazole derivatives using iron dust

Doi:10.1002/jhet.418
(2010)
Synthesis of new 3-substituted indole derivatives

Doi:10.1515/znb-2010-1213
(2010)
Electron-deficient aryl β-diketones: Synthesis and novel tautomeric preferences

Doi:10.1002/ejoc.201001451
(2011)
Design, synthesis and docking study of 5-amino substituted indeno[1,2-c]isoquinolines as novel topoisomerase i inhibitors

Doi:10.1016/j.bmc.2011.01.064
(2011)
A simple one-pot synthesis of isoflavanones

Doi:10.1080/00397919908085910
(1999)

Article Doi