Tetrahedron Letters p. 1323 - 1326 (1990)
Update date:2022-07-31
Topics:
Secen, Hasan
Suetbeyaz, Yasar
Balci, Metin
A new and stereospecific synthesis for conduritol-F has been developed starting from trans-benzenediacetate 5 and oxepine-benzeneoxide 8 where the oxygen functionalities were introduced in both cases by photooxygenation; suitable ring opening reactions gave the desired conduritol-F.Acid-catalyzed ring opening reaction of 11 in acetic anhydride gave conduritol-F and conduritol-B in a ratio of 2:1.
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