GENERATION AND FATE OF NONDECARBOXYLATING ACYLOXY RADICALS DERIVED FROM THE PHOTOLYSIS OF ACYL DERIVATIVES OF N-HYDROXY-2-THIOPYRIDONE

DOI: 10.1016/S0040-4039(00)94400-9

Source and publish data:

Tetrahedron Letters p. 949 - 952 (1990)

Update date:2022-08-04

Topics:

Authors:

Barton, Derek H. R.

Ramesh, Manian

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Article abstract of DOI:10.1016/S0040-4039(00)94400-9

The acyl derivatives of 1 with the acyl group linked to aryl, vinyl etc. give on photolysis carboxy radicals.These radicals, by attack on the thiopyridone function, afford thio-peresters which are the real precursors of the anhydrides observed before.The benzoyloxy radical from 2 can be trapped by ethylvinyl ether to give adduct 14 in promising yield.

Full text of DOI:10.1016/S0040-4039(00)94400-9

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