TOTAL SYNTHESIS OF (+/-)-AGELINE A, A PHYSIOLOGICALLY ACTIVE CONSTITUENT OF AGELAS SPONGES

DOI: 10.1016/S0040-4039(01)93906-1

Source and publish data:

Tetrahedron Letters p. 6401 - 6404 (1989)

Update date:2022-08-03

Topics: Characterization functional group interconversions Purification Retrosynthetic analysis Stereochemistry Control Biological Evaluation Final assembly Synthesis of Fragments Coupling reactions

Authors:

Asao, Kazuhiko

Iio, Hideo

Tokoroyama, Takashi

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Article abstract of DOI:10.1016/S0040-4039(01)93906-1

The monocyclic diterpene moiety of ageline A (1) was convergently constructed by the palladium-mediated coupling of C9-terpenic chain as vinyl bromide 10 and C11-monocyclic segment as alkylzinc compound 16, which was obtained through a stereoselective cyc

Full text of DOI:10.1016/S0040-4039(01)93906-1

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