Asymmetric Synthesis of Pipecolic Acid Derivatives Using the Aza-Diels-Alder Reaction

DOI: 10.1016/S0957-4166(00)80025-7

Source and publish data:

Tetrahedron Asymmetry p. 1263 - 1282 (1991)

Update date:2022-08-02

Topics: Characterization applications Workup and Isolation Scale-up Reaction Conditions Selection of Starting Materials Chiral Catalyst

Authors:

Bailey, Patrick D.

Brown, George R.

Korber, Fritjof

Reed, Amanda

Wilson, Robert D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0957-4166(00)80025-7

Imines of the type R-N=CHCO2Et can be coerced into undergoing a (4+2) cycloaddition with substituted dienes if the reaction is carried out in DMF in the presence of both water and acid; these reactions show extremely high regio- and diastereoselectivity.U

Full text of DOI:10.1016/S0957-4166(00)80025-7

Products guided by the article

Product name:(2R/S,5S/R,6R/S)-1-benzyl-6-ethoxycarbonyl-2,5-dimethyl-3,4-didehydropiperidine

Cas No:127897-26-1

R&D Labs maybe for 127897-26-1

Tai zhou world Pharm & Chem Co., Ltd

Contact:+86-576-85301198

Address:Rome 1001,wangjiang plaza,unti 2,jinshan east Road linhai,zhejiang,china
Hunan Shineway Enterprise Co., Ltd.

Contact:+86-731-86303875

Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China
EGBERT CORPORATION

Contact:+86 18616952870

Address:Area
Hangzhou Hysen Pharma co.,Ltd.

website:http://www.hysenpharma.cn/

Contact:0086-571-88298791

Address:#701,Gudun Road Hangzhou
NingBO Hong Xiang Biochem.Co.Ltd

website:http://www.hxbiochem.com

Contact:0574-66003444

Address:Ning Bo Bei Lun

Relevant to this article

Sulfur-directed olefin oxidations: Observation of divergent reaction mechanisms in the palladium-mediated acetoxylation of unsaturated thioacetals

Doi:10.1021/om2000585
(2011)
UNUSUAL ORIENTATION IN VICARIOUS NUCLEOPHILIC SUBSTITUTION OF HYDROGEN IN NITROPYRROLES

Doi:10.1016/S0040-4039(00)94350-8
(1990)
Palladium-Catalyzed Cascade Approach to 12-(Aryl)indolo[1,2- c ]quinazolin-6(5 H)-ones

Doi:10.1055/s-0036-1589158
(2018)
Nickel-catalysed synthesis of 3-chloroanilines and chloro aminopyridines via cross-coupling reactions of aryl and heteroaryl dichlorides with amines

Doi:10.1016/S0040-4039(00)01931-6
(2001)
Regioselective synthesis of 2-arylidene coumaran-3-ones by dye-sensitized photooxygenation of 2-hydroxyphenyl-styrylketones in the presence of sodium dodecyl sulphate

Doi:10.1016/S0040-4020(01)81970-0
(1990)
Total Synthesis of Mycalamides A and B

Doi:10.1021/jo00301a007
(1990)

Article Doi