UNUSUAL ORIENTATION IN VICARIOUS NUCLEOPHILIC SUBSTITUTION OF HYDROGEN IN NITROPYRROLES

DOI: 10.1016/S0040-4039(00)94350-8

Source and publish data:

Tetrahedron Letters p. 121 - 122 (1990)

Update date:2022-08-02

Topics:

Authors:

Kwast, Ewa

Makosza, Mieczyslaw

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Article abstract of DOI:10.1016/S0040-4039(00)94350-8

The vicarious nucleophilic substitution of hydrogen in N-substituted 2-nitropyrrole with carbanion of chloromethyl phenyl sulfone occurs at position 5- or 3- depending upon electronic effects of the N-protecting group.

Full text of DOI:10.1016/S0040-4039(00)94350-8

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