Cycloadditions between Electron-poor Phospha-alkene Complexes and Electron-rich Alkenes or Alkynes: A New Route to Phosphetane and 1,2-Dihydrophosphete Rings

DOI: 10.1039/c39900000153

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 153 - 154 (1990)

Update date:2022-08-02

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Authors:

Marinetti, Angela

Mathey, Francois

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Article abstract of DOI:10.1039/c39900000153

Ethoxycarbonyl-C-substituted phospha-alkene P-W(CO)5 complexes instantly react at low temperature with enamines, enol ethers, ynamines, and ethoxyacetylene to yield the corresponding phosphetane and 1,2-dihydrophosphete <2 + 2> cycloadducts.

Full text of DOI:10.1039/c39900000153

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