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Lipase Catalysed Regio- and Enantio-selective Hydrolysis: Molecular Recognition Phenomenon and Synthesis of (R)-Dimorphecolic Acid

DOI: 10.1039/c39910001197

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1197 - 1198 (1991)

Update date:2022-08-04

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Authors:

Bhalerao, U. T.Bhalerao, U. T.

Dasaradhi, L.Dasaradhi, L.

Neelakantan, P.Neelakantan, P.

Fadnavis, N. W.Fadnavis, N. W.

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Article abstract of DOI:10.1039/c39910001197

Molecular recognition has been observed in hydrolysis of racemic esters of (E)-9=acetoxy-11-bromoundec-10-enoic acid by a lipase of Candida cylindracea (E.C. 3.1.1.3) where optically active (R)-(E)-9-acetoxy-11-bromoundec-10-enoic acid 99percent> was obtained which was used in synthesis of (R)-dimorphecolic acid.

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