Tetrahedron Letters p. 571 - 574 (1995)
Update date:2022-09-26
Topics:
Hojo, Makoto
Fujii, Atsuko
Murakami, Chikara
Aihara, Hidenori
Hosomi, Akira
α,β-Epoxy ketones are reduced by trimethoxysilane in the presence of a catalytic amount of lithium melboxide to yield the corresponding alcohols. This reaction system reveals divergent selectivity depending on the solvent; both anti-selectivity and syn-se
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