SYNTHESIS OF ENANTIOMERICALLY PURE 2,3-DIDEOXY-HEPT-2-ENONO-1,4-LACTONE DERIVATIVES VIA DIASTEREOSELECTIVE ADDITION OF 2-(TRIMETHYLSILOXY)FURAN TO D-GLYCERALDEHYDE AND D-SERINAL-BASED THREE-CARBON SYNTHONS

DOI: 10.1016/S0040-4039(01)93777-3

Source and publish data:

Tetrahedron Letters p. 5325 - 5328 (1989)

Update date:2022-08-02

Topics:

Authors:

Casiraghi, Giovanni

Colombo, Lino

Rassu, Gloria

Spanu, Pietro

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Article abstract of DOI:10.1016/S0040-4039(01)93777-3

The BF3-promoted addition of 2-(trimethylsiloxy)furan to 2,3-O-isopropylidene-D-glyceraldehyde and N-t-BOC-D-serinal, and the corresponding imine derivatives gives the title seven-carbon lactones with great preference for the D-arabino diastereoisomers.

Full text of DOI:10.1016/S0040-4039(01)93777-3

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