A VERSATILE PROTOCOL FOR β-HYDROXY-α-AMINO ACIDS: AN APPLICATION TO (4R)-4--4,N-DIMETHYL-L-THREONINE (MeBmt)

DOI: 10.1016/S0040-4020(01)89197-3

Source and publish data:

Tetrahedron p. 7361 - 7370 (1989)

Update date:2022-08-03

Topics:

Authors:

Rao, A. V. Rama

Dhar, T. G. Murali

Bose, D. Subhas

Chakraborty, T. K.

Gurjar, M. K.

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Article abstract of DOI:10.1016/S0040-4020(01)89197-3

cis-Oxazolidinone derivative (30) readily realised from chiral 2,3-epoxy alcohol (27) had been exploited in the synthesis of (4R)-4-<(E)-2-butenyl>-4,N-dimethyl-L-threonine (2), an unusual β-hydroxy-α-amino acid present in cyclosporin.The intrinsic featur

Full text of DOI:10.1016/S0040-4020(01)89197-3

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